I like to analyze at the character of Alicia Florrick in three eras: before her husband's affair, emerging independence, and her current state of confidence and leadership. In her three eras I have identified her by what scents I think she would have worn during them.
In her era before she knew of Peter's affairs I think she wore Donna Karan's Cashmere Mist. It is a comfortable scent that signify's a certain amount of my domain is domestic affairs and I am very good at what I do there. Still it is one of the smarter maternal scents out there, the structure powdery and dry with a uniquely cool jasmine note.
After the scandal of Peter's affairs coming to light, I feel that Alicia probably wanted a scent that had more armor, oomph, and intellect. She was once again a part of the job force and having to stretch her intellectual and balancing muscles. With the new status of being a lawyer again and being able to support herself and her family I think she would wear a scent like Balenciaga's Paris. Balenciaga's Paris is a mix of violet in all its forms with a cool green mossy fougere note running through it and just a hint of sweetness from a very subtle raspberry note. It is a scent that signifies determination, elegance, and business all the things that Alicia embodies at that period.
The the current era is signified by the key turning point in Alicia's life: her affair with Will Gardner. The affair demands change considering it allows Alicia to once again become sexual and completely lets her step out of her duty of being "the good wife." Her assertiveness in her life is more obvious and she isn't shying away from showing it in her personal and business life. For Alicia's current era of life I think she is wearing Serge Luten's Feminite du Bois. The scent continues the violet theme found in Balenciaga's Paris but this violet has woods, musk, spices, and plum. The scent is more opulent, assertive, but it is also sensual. It is not an obvious sensual scent, Alicia is never one for the obvious, but there is no denying that Feminite du Bois is alluring in its use of woods and spices. It remains subtle enough that no one can question the appropriateness of it but up close the warmth of the notes suggests warm skin.
image from Tvholic